Solid state debromination of C 60 Br 24 back to C 60 with cesium iodide: kinetics, thermodynamics and mechanism
The bromofullerene C60Br24 undergoes a complete and quantitative debromination to C60 when it is mixed and ground in the solid state with cesium iodide (CsI). The kinetics of this unique solid state debromination reaction was studied with FT-IR spectroscopy on C60Br24 embedded in CsI pellet. The debromination rate constant was measured k = 8.4 x 10
Barzaga, Ransel et al.
Fecha de publicación:
3
2024